Insulated gold scanning tunneling microscopy probes for recognition tunneling in an aqueous environment.

Surface reactions of gold(111) with aqueous cyanide studied by scanning tunneling microscopy

DNA probes on chip surfaces studied by scanning force microscopy using specific binding of colloidal gold.

Single-stranded DNA was covalently bound on chip surfaces using two different silanization procedures. The resulting surfaces were characterized by fluorescence and scanning force microscopy using sequence-complementary DNA molecules with labels. Colloidal gold (30 nm) was used as the topographic label. Scanning force microscopy revealed the individual labels on the surface and their distributi...

STM-electroluminescence probes of metallic and polymeric materials

The STM-electroluminescence technique is shown to be a valuable tool for characterizing optoelectronic properties and understanding structure-function relationships in heterogeneous or disordered materials on nanometer length scales. The intensity of photon emission induced by tunneling electrons from rough Au films is found to depend on the surface feature size. This size-dependent photon emis...

An approach to long-range electron transfer mechanisms in metalloproteins: in situ scanning tunneling microscopy with submolecular resolution.

In situ scanning tunneling microscopy (STM) of redox molecules, in aqueous solution, shows interesting analogies and differences compared with interfacial electrochemical electron transfer (ET) and ET in homogeneous solution. This is because the redox level represents a deep indentation in the tunnel barrier, with possible temporary electronic population. Particular perspectives are that both t...

Scanning tunneling microscopy applied to optical surfaces.

The technique of scanning tunneling microscopy has been applied to topographic mapping of two optical surfaces: a ruled grating replica and a diamond-turned gold mirror. We have demonstrated the ability of the scanning tunneling microscope to measure surface topography of a ruled-grating replica over an area of 2 microm x 2 microm. Furthermore, surface structure on a diamond-turned gold mirror ...